Resonant cavity gas-phase polarimeter

Jérôme Poirson; Marc Vallet; Fabien Bretenaker; Albert Le Floch; Jean Yves Thépot

doi:10.1021/ac980286e

Resonant cavity gas-phase polarimeter

Jérôme Poirson
, Marc Vallet
, Fabien Bretenaker
, Albert Le Floch
, Jean Yves Thépot

École Polytechnique

CNRS
Institut des Sciences Chimiques de Rennes

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

26 Citations (Scopus)

Résumé

A high-sensitivity polarimeter is demonstrated for application to gas-phase chirality measurement. This device is based on the physics of the eigenstates of a Fabry-Perot cavity, permitting improvement in the sensitivity with respect to the usual polarimeters. Typical measurements of rotations of 50 (±1) x 10^-5° induced by the optical activity of (R)-(+)-limonene and (S)-(-)-limonene in the vapor phase are shown. A noise level corresponding to a rotation of 10^-6° is experimentally demonstrated. Application to the polarimetric monitoring of an enantiomer mixing racemization of limonene in the gas phase is also presented.

langue originale	Anglais
Pages (de - à)	4636-4639
Nombre de pages	4
journal	Analytical Chemistry
Volume	70
Numéro de publication	21
Les DOIs	https://doi.org/10.1021/ac980286e
état	Publié - 1 nov. 1998

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10.1021/ac980286e

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@article{b17624782a7d47909f1896bdc5313d70,

title = "Resonant cavity gas-phase polarimeter",

abstract = "A high-sensitivity polarimeter is demonstrated for application to gas-phase chirality measurement. This device is based on the physics of the eigenstates of a Fabry-Perot cavity, permitting improvement in the sensitivity with respect to the usual polarimeters. Typical measurements of rotations of 50 (±1) x 10-5° induced by the optical activity of (R)-(+)-limonene and (S)-(-)-limonene in the vapor phase are shown. A noise level corresponding to a rotation of 10-6° is experimentally demonstrated. Application to the polarimetric monitoring of an enantiomer mixing racemization of limonene in the gas phase is also presented.",

author = "J{\'e}r{\^o}me Poirson and Marc Vallet and Fabien Bretenaker and \{Le Floch\}, Albert and Th{\'e}pot, \{Jean Yves\}",

year = "1998",

month = nov,

day = "1",

doi = "10.1021/ac980286e",

language = "English",

volume = "70",

pages = "4636--4639",

journal = "Analytical Chemistry",

issn = "0003-2700",

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TY - JOUR

T1 - Resonant cavity gas-phase polarimeter

AU - Poirson, Jérôme

AU - Vallet, Marc

AU - Bretenaker, Fabien

AU - Le Floch, Albert

AU - Thépot, Jean Yves

PY - 1998/11/1

Y1 - 1998/11/1

N2 - A high-sensitivity polarimeter is demonstrated for application to gas-phase chirality measurement. This device is based on the physics of the eigenstates of a Fabry-Perot cavity, permitting improvement in the sensitivity with respect to the usual polarimeters. Typical measurements of rotations of 50 (±1) x 10-5° induced by the optical activity of (R)-(+)-limonene and (S)-(-)-limonene in the vapor phase are shown. A noise level corresponding to a rotation of 10-6° is experimentally demonstrated. Application to the polarimetric monitoring of an enantiomer mixing racemization of limonene in the gas phase is also presented.

AB - A high-sensitivity polarimeter is demonstrated for application to gas-phase chirality measurement. This device is based on the physics of the eigenstates of a Fabry-Perot cavity, permitting improvement in the sensitivity with respect to the usual polarimeters. Typical measurements of rotations of 50 (±1) x 10-5° induced by the optical activity of (R)-(+)-limonene and (S)-(-)-limonene in the vapor phase are shown. A noise level corresponding to a rotation of 10-6° is experimentally demonstrated. Application to the polarimetric monitoring of an enantiomer mixing racemization of limonene in the gas phase is also presented.

U2 - 10.1021/ac980286e

DO - 10.1021/ac980286e

M3 - Article

AN - SCOPUS:0010504603

SN - 0003-2700

VL - 70

SP - 4636

EP - 4639

JO - Analytical Chemistry

JF - Analytical Chemistry

IS - 21

ER -

Resonant cavity gas-phase polarimeter

Résumé

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