Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium

Grégory Nocton; Louis Ricard

doi:10.1039/c5cc00289c

Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium

Grégory Nocton
, Louis Ricard

CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

40 Citations (Scopus)

Résumé

The reaction of a series of organolanthanide fragments of samarium and thulium with phenanthroline is reported. All adducts couple in the 4-position of the phenanthroline ligand to yield the 4-4′ dimers when they crystallize. The analysis of the solution structure revealed a thermally reversible C-C coupling in all cases.

langue originale	Anglais
Pages (de - à)	3578-3581
Nombre de pages	4
journal	Chemical Communications
Volume	51
Numéro de publication	17
Les DOIs	https://doi.org/10.1039/c5cc00289c
état	Publié - 28 févr. 2015
Modification externe	Oui

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10.1039/c5cc00289c

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title = "Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium",

abstract = "The reaction of a series of organolanthanide fragments of samarium and thulium with phenanthroline is reported. All adducts couple in the 4-position of the phenanthroline ligand to yield the 4-4′ dimers when they crystallize. The analysis of the solution structure revealed a thermally reversible C-C coupling in all cases.",

author = "Gr{\'e}gory Nocton and Louis Ricard",

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T1 - Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium

AU - Nocton, Grégory

AU - Ricard, Louis

PY - 2015/2/28

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N2 - The reaction of a series of organolanthanide fragments of samarium and thulium with phenanthroline is reported. All adducts couple in the 4-position of the phenanthroline ligand to yield the 4-4′ dimers when they crystallize. The analysis of the solution structure revealed a thermally reversible C-C coupling in all cases.

AB - The reaction of a series of organolanthanide fragments of samarium and thulium with phenanthroline is reported. All adducts couple in the 4-position of the phenanthroline ligand to yield the 4-4′ dimers when they crystallize. The analysis of the solution structure revealed a thermally reversible C-C coupling in all cases.

U2 - 10.1039/c5cc00289c

DO - 10.1039/c5cc00289c

M3 - Article

AN - SCOPUS:84923166775

SN - 1359-7345

VL - 51

SP - 3578

EP - 3581

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium

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