Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

Ravi Yadav; Thomas Simler; Michael T. Gamer; Ralf Köppe; Peter W. Roesky

doi:10.1039/c9cc02350j

Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

Ravi Yadav
, Thomas Simler
, Michael T. Gamer
, Ralf Köppe
, Peter W. Roesky

Institute of Meteorology and Climate Research

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The reduction of M₂(CO)₁₀ (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.

langue originale	Anglais
Pages (de - à)	5765-5768
Nombre de pages	4
journal	Chemical Communications
Volume	55
Numéro de publication	41
Les DOIs	https://doi.org/10.1039/c9cc02350j
état	Publié - 1 janv. 2019
Modification externe	Oui

Accès au document

10.1039/c9cc02350j

Autres fichiers et liens

Lien vers la publication dans Scopus

Contient cette citation

@article{5e16ef52f88e48628cbd4fd64fc0ecbc,

title = "Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls",

abstract = "The reduction of M2(CO)10 (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.",

author = "Ravi Yadav and Thomas Simler and Gamer, \{Michael T.\} and Ralf K{\"o}ppe and Roesky, \{Peter W.\}",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

month = jan,

day = "1",

doi = "10.1039/c9cc02350j",

language = "English",

volume = "55",

pages = "5765--5768",

journal = "Chemical Communications",

issn = "1359-7345",

number = "41",

}

TY - JOUR

T1 - Rhenium is different

T2 - CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

AU - Yadav, Ravi

AU - Simler, Thomas

AU - Gamer, Michael T.

AU - Köppe, Ralf

AU - Roesky, Peter W.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - The reduction of M2(CO)10 (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.

AB - The reduction of M2(CO)10 (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.

UR - https://www.scopus.com/pages/publications/85065860070

U2 - 10.1039/c9cc02350j

DO - 10.1039/c9cc02350j

M3 - Article

C2 - 31038498

AN - SCOPUS:85065860070

SN - 1359-7345

VL - 55

SP - 5765

EP - 5768

JO - Chemical Communications

JF - Chemical Communications

IS - 41

ER -

Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Contient cette citation