Room-Temperature Pd-Catalyzed Synthesis of 1-(Hetero)aryl Selenoglycosides

Mingxiang Zhu; Mouad Alami; Samir Messaoudi

doi:10.1021/acs.orglett.0c02352

Room-Temperature Pd-Catalyzed Synthesis of 1-(Hetero)aryl Selenoglycosides

Mingxiang Zhu
, Mouad Alami
, Samir Messaoudi

Université Paris-Sud

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

A general protocol for functionalization of an anomeric selonate anion at room temperature has been reported. By using the PdG3 XantPhos catalyst, the cross-coupling between the in situ-generated glycosyl selenolate and a broad range of (hetero)aryl and alkenyl iodides furnished a series of functionalized selenoglycosides in excellent yields with perfect control of the anomeric configuration.

langue originale	Anglais
Pages (de - à)	6584-6589
Nombre de pages	6
journal	Organic Letters
Volume	22
Numéro de publication	16
Les DOIs	https://doi.org/10.1021/acs.orglett.0c02352
état	Publié - 21 août 2020
Modification externe	Oui

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10.1021/acs.orglett.0c02352

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title = "Room-Temperature Pd-Catalyzed Synthesis of 1-(Hetero)aryl Selenoglycosides",

abstract = "A general protocol for functionalization of an anomeric selonate anion at room temperature has been reported. By using the PdG3 XantPhos catalyst, the cross-coupling between the in situ-generated glycosyl selenolate and a broad range of (hetero)aryl and alkenyl iodides furnished a series of functionalized selenoglycosides in excellent yields with perfect control of the anomeric configuration.",

author = "Mingxiang Zhu and Mouad Alami and Samir Messaoudi",

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AU - Alami, Mouad

AU - Messaoudi, Samir

PY - 2020/8/21

Y1 - 2020/8/21

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AB - A general protocol for functionalization of an anomeric selonate anion at room temperature has been reported. By using the PdG3 XantPhos catalyst, the cross-coupling between the in situ-generated glycosyl selenolate and a broad range of (hetero)aryl and alkenyl iodides furnished a series of functionalized selenoglycosides in excellent yields with perfect control of the anomeric configuration.

UR - https://www.scopus.com/pages/publications/85089787145

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DO - 10.1021/acs.orglett.0c02352

M3 - Article

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AN - SCOPUS:85089787145

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EP - 6589

JO - Organic Letters

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Room-Temperature Pd-Catalyzed Synthesis of 1-(Hetero)aryl Selenoglycosides

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