Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

Grégory Danoun; Bilguun Bayarmagnai; Matthias F. Gruenberg; Lukas J. Goossen

doi:10.1039/c3sc53076k

Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

Grégory Danoun
, Bilguun Bayarmagnai
, Matthias F. Gruenberg
, Lukas J. Goossen

University of Kaiserslautern

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

In the presence of copper thiocyanate, sodium thiocyanate and the inexpensive, easy-to-use trifluoromethylating reagent Me₃Si–CF₃, diazonium salts are smoothly converted into the corresponding aryl trifluoromethyl thioethers. Combined with diazotisation, this convenient and inexpensive method allows the straightforward synthesis of aryl or heteroaryl trifluoromethyl thioethers from the corresponding anilines.

langue originale	Anglais
Pages (de - à)	1312-1316
Nombre de pages	5
journal	Chemical Science
Volume	5
Numéro de publication	4
Les DOIs	https://doi.org/10.1039/c3sc53076k
état	Publié - 3 mars 2014
Modification externe	Oui

Accès au document

10.1039/c3sc53076k

Contient cette citation

@article{1294faec816646f9be968e710752fd37,

title = "Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent",

abstract = "In the presence of copper thiocyanate, sodium thiocyanate and the inexpensive, easy-to-use trifluoromethylating reagent Me3Si–CF3, diazonium salts are smoothly converted into the corresponding aryl trifluoromethyl thioethers. Combined with diazotisation, this convenient and inexpensive method allows the straightforward synthesis of aryl or heteroaryl trifluoromethyl thioethers from the corresponding anilines.",

author = "Gr{\'e}gory Danoun and Bilguun Bayarmagnai and Gruenberg, \{Matthias F.\} and Goossen, \{Lukas J.\}",

year = "2014",

month = mar,

day = "3",

doi = "10.1039/c3sc53076k",

language = "English",

volume = "5",

pages = "1312--1316",

journal = "Chemical Science",

issn = "2041-6520",

number = "4",

}

TY - JOUR

T1 - Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

AU - Danoun, Grégory

AU - Bayarmagnai, Bilguun

AU - Gruenberg, Matthias F.

AU - Goossen, Lukas J.

PY - 2014/3/3

Y1 - 2014/3/3

N2 - In the presence of copper thiocyanate, sodium thiocyanate and the inexpensive, easy-to-use trifluoromethylating reagent Me3Si–CF3, diazonium salts are smoothly converted into the corresponding aryl trifluoromethyl thioethers. Combined with diazotisation, this convenient and inexpensive method allows the straightforward synthesis of aryl or heteroaryl trifluoromethyl thioethers from the corresponding anilines.

AB - In the presence of copper thiocyanate, sodium thiocyanate and the inexpensive, easy-to-use trifluoromethylating reagent Me3Si–CF3, diazonium salts are smoothly converted into the corresponding aryl trifluoromethyl thioethers. Combined with diazotisation, this convenient and inexpensive method allows the straightforward synthesis of aryl or heteroaryl trifluoromethyl thioethers from the corresponding anilines.

U2 - 10.1039/c3sc53076k

DO - 10.1039/c3sc53076k

M3 - Article

AN - SCOPUS:84897729940

SN - 2041-6520

VL - 5

SP - 1312

EP - 1316

JO - Chemical Science

JF - Chemical Science

IS - 4

ER -

Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

Résumé

Accès au document

Empreinte digitale

Contient cette citation