Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones

L. D. Miranda; S. Z. Zard

doi:10.1039/b101053k

Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones

L. D. Miranda
, S. Z. Zard

CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The previously described, highly stereoselective ring-closure of δ-unsaturated tosylhydrazones upon reduction with borohydride may not be a radical process but rather an enetype concerted transformation of the intermediate mono-substituted diimide.

langue originale	Anglais
Pages (de - à)	1068-1069
Nombre de pages	2
journal	Chemical Communications
Numéro de publication	12
Les DOIs	https://doi.org/10.1039/b101053k
état	Publié - 21 juin 2001

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10.1039/b101053k

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abstract = "The previously described, highly stereoselective ring-closure of δ-unsaturated tosylhydrazones upon reduction with borohydride may not be a radical process but rather an enetype concerted transformation of the intermediate mono-substituted diimide.",

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Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones

Résumé

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