Stereospecificity in radical carbon-carbon bond formation reactions based on tartaric acid

Derek H.R. Barton; Alice Gateau-Olesker; Stephan D. Gero; Brigitte Lacher; Catherine Tachdjian; Samir Z. Zard

doi:10.1039/C39870001790

Stereospecificity in radical carbon-carbon bond formation reactions based on tartaric acid

Derek H.R. Barton
, Alice Gateau-Olesker
, Stephan D. Gero
, Brigitte Lacher
, Catherine Tachdjian
, Samir Z. Zard

Institut de Chimie des Substances Naturelles
Texas A&M University

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Radical decarboxylative addition to activated alkenes, using the thiohydroxamic ester method, of a suitably protected derivative of (+)-L-tartaric acid leads to overall substitution of the carboxy group with essentially complete retention of configuration.

langue originale	Anglais
Pages (de - à)	1790-1792
Nombre de pages	3
journal	Journal of the Chemical Society, Chemical Communications
Numéro de publication	23
Les DOIs	https://doi.org/10.1039/C39870001790
état	Publié - 1 déc. 1987
Modification externe	Oui

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10.1039/C39870001790

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@article{330450baf1fc4850a56e52a47648ce44,

title = "Stereospecificity in radical carbon-carbon bond formation reactions based on tartaric acid",

abstract = "Radical decarboxylative addition to activated alkenes, using the thiohydroxamic ester method, of a suitably protected derivative of (+)-L-tartaric acid leads to overall substitution of the carboxy group with essentially complete retention of configuration.",

author = "Barton, \{Derek H.R.\} and Alice Gateau-Olesker and Gero, \{Stephan D.\} and Brigitte Lacher and Catherine Tachdjian and Zard, \{Samir Z.\}",

year = "1987",

month = dec,

day = "1",

doi = "10.1039/C39870001790",

language = "English",

pages = "1790--1792",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

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TY - JOUR

T1 - Stereospecificity in radical carbon-carbon bond formation reactions based on tartaric acid

AU - Barton, Derek H.R.

AU - Gateau-Olesker, Alice

AU - Gero, Stephan D.

AU - Lacher, Brigitte

AU - Tachdjian, Catherine

AU - Zard, Samir Z.

PY - 1987/12/1

Y1 - 1987/12/1

N2 - Radical decarboxylative addition to activated alkenes, using the thiohydroxamic ester method, of a suitably protected derivative of (+)-L-tartaric acid leads to overall substitution of the carboxy group with essentially complete retention of configuration.

AB - Radical decarboxylative addition to activated alkenes, using the thiohydroxamic ester method, of a suitably protected derivative of (+)-L-tartaric acid leads to overall substitution of the carboxy group with essentially complete retention of configuration.

UR - https://www.scopus.com/pages/publications/37049082016

U2 - 10.1039/C39870001790

DO - 10.1039/C39870001790

M3 - Article

AN - SCOPUS:37049082016

SN - 0022-4936

SP - 1790

EP - 1792

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 23

ER -

Stereospecificity in radical carbon-carbon bond formation reactions based on tartaric acid

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