Strong chiroptical effects in surface second harmonic generation obtained for molecules exhibiting excitonic coupling chirality

M. C. Schanne-Klein; T. Boulesteix; F. Hache; M. Alexandre; G. Lemercier; C. Andraud

doi:10.1016/S0009-2614(02)01030-8

Strong chiroptical effects in surface second harmonic generation obtained for molecules exhibiting excitonic coupling chirality

M. C. Schanne-Klein
, T. Boulesteix
, F. Hache
, M. Alexandre
, G. Lemercier
, C. Andraud

Institut Polytechnique de Paris
Ecole Normale Supérieure de Lyon

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

23 Citations (Scopus)

Résumé

We measured nonlinear optical activity in second harmonic generation (SHG) by reflection on a thin film of chiral molecules. We selected the structure of our molecules in order to obtain very large chiroptical effects. We indeed measured an angle of rotation of the second harmonic polarization as large as 66° for an acridine substituted Tröger base. This is in good agreement with our theoretical expectations for such an excitonic coupling chirality.

langue originale	Anglais
Pages (de - à)	103-108
Nombre de pages	6
journal	Chemical Physics Letters
Volume	362
Numéro de publication	1-2
Les DOIs	https://doi.org/10.1016/S0009-2614(02)01030-8
état	Publié - 13 août 2002

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10.1016/S0009-2614(02)01030-8

Contient cette citation

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title = "Strong chiroptical effects in surface second harmonic generation obtained for molecules exhibiting excitonic coupling chirality",

abstract = "We measured nonlinear optical activity in second harmonic generation (SHG) by reflection on a thin film of chiral molecules. We selected the structure of our molecules in order to obtain very large chiroptical effects. We indeed measured an angle of rotation of the second harmonic polarization as large as 66° for an acridine substituted Tr{\"o}ger base. This is in good agreement with our theoretical expectations for such an excitonic coupling chirality.",

author = "Schanne-Klein, \{M. C.\} and T. Boulesteix and F. Hache and M. Alexandre and G. Lemercier and C. Andraud",

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T1 - Strong chiroptical effects in surface second harmonic generation obtained for molecules exhibiting excitonic coupling chirality

AU - Schanne-Klein, M. C.

AU - Boulesteix, T.

AU - Hache, F.

AU - Alexandre, M.

AU - Lemercier, G.

AU - Andraud, C.

PY - 2002/8/13

Y1 - 2002/8/13

N2 - We measured nonlinear optical activity in second harmonic generation (SHG) by reflection on a thin film of chiral molecules. We selected the structure of our molecules in order to obtain very large chiroptical effects. We indeed measured an angle of rotation of the second harmonic polarization as large as 66° for an acridine substituted Tröger base. This is in good agreement with our theoretical expectations for such an excitonic coupling chirality.

AB - We measured nonlinear optical activity in second harmonic generation (SHG) by reflection on a thin film of chiral molecules. We selected the structure of our molecules in order to obtain very large chiroptical effects. We indeed measured an angle of rotation of the second harmonic polarization as large as 66° for an acridine substituted Tröger base. This is in good agreement with our theoretical expectations for such an excitonic coupling chirality.

U2 - 10.1016/S0009-2614(02)01030-8

DO - 10.1016/S0009-2614(02)01030-8

M3 - Article

AN - SCOPUS:0037072320

SN - 0009-2614

VL - 362

SP - 103

EP - 108

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2

ER -

Strong chiroptical effects in surface second harmonic generation obtained for molecules exhibiting excitonic coupling chirality

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