Synthesis and photovoltaic properties of mono-substituted quaterthiophenes bearing strong electron-withdrawing group

Abderrahim Yassar; Christine Videlot; Abdelhafid Jaafari

doi:10.1016/j.solmat.2005.05.011

Synthesis and photovoltaic properties of mono-substituted quaterthiophenes bearing strong electron-withdrawing group

Abderrahim Yassar
, Christine Videlot
, Abdelhafid Jaafari

Université Paris Diderot
Aix-Marseille Université
Université Hassan 1er

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

25 Citations (Scopus)

Résumé

We report here on the synthesis and properties of a monosubstituted quaterthiophene derivative asymmetrically functionalized by an electron-withdrawing group using the palladium-catalyzed Stille's coupling reaction. The UV-vis absorption spectrum evidences a strong intramolecular charge transfer transition. Thus oligothiophenes act as electron donors and substituent group as acceptor. The diodes in which monosubstituted quaterthiophenes behave as organic semiconductors, exhibit a rectifying behavior. Photovoltaic measurements show moderate power conversion efficiency.

langue originale	Anglais
Pages (de - à)	916-922
Nombre de pages	7
journal	Solar Energy Materials and Solar Cells
Volume	90
Numéro de publication	7-8
Les DOIs	https://doi.org/10.1016/j.solmat.2005.05.011
état	Publié - 5 mai 2006
Modification externe	Oui

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10.1016/j.solmat.2005.05.011

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title = "Synthesis and photovoltaic properties of mono-substituted quaterthiophenes bearing strong electron-withdrawing group",

abstract = "We report here on the synthesis and properties of a monosubstituted quaterthiophene derivative asymmetrically functionalized by an electron-withdrawing group using the palladium-catalyzed Stille's coupling reaction. The UV-vis absorption spectrum evidences a strong intramolecular charge transfer transition. Thus oligothiophenes act as electron donors and substituent group as acceptor. The diodes in which monosubstituted quaterthiophenes behave as organic semiconductors, exhibit a rectifying behavior. Photovoltaic measurements show moderate power conversion efficiency.",

keywords = "Oligothiophenes, Organic photovoltaic, Organic semiconductors, Quaterthiophenes",

author = "Abderrahim Yassar and Christine Videlot and Abdelhafid Jaafari",

year = "2006",

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doi = "10.1016/j.solmat.2005.05.011",

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TY - JOUR

T1 - Synthesis and photovoltaic properties of mono-substituted quaterthiophenes bearing strong electron-withdrawing group

AU - Yassar, Abderrahim

AU - Videlot, Christine

AU - Jaafari, Abdelhafid

PY - 2006/5/5

Y1 - 2006/5/5

N2 - We report here on the synthesis and properties of a monosubstituted quaterthiophene derivative asymmetrically functionalized by an electron-withdrawing group using the palladium-catalyzed Stille's coupling reaction. The UV-vis absorption spectrum evidences a strong intramolecular charge transfer transition. Thus oligothiophenes act as electron donors and substituent group as acceptor. The diodes in which monosubstituted quaterthiophenes behave as organic semiconductors, exhibit a rectifying behavior. Photovoltaic measurements show moderate power conversion efficiency.

AB - We report here on the synthesis and properties of a monosubstituted quaterthiophene derivative asymmetrically functionalized by an electron-withdrawing group using the palladium-catalyzed Stille's coupling reaction. The UV-vis absorption spectrum evidences a strong intramolecular charge transfer transition. Thus oligothiophenes act as electron donors and substituent group as acceptor. The diodes in which monosubstituted quaterthiophenes behave as organic semiconductors, exhibit a rectifying behavior. Photovoltaic measurements show moderate power conversion efficiency.

KW - Oligothiophenes

KW - Organic photovoltaic

KW - Organic semiconductors

KW - Quaterthiophenes

U2 - 10.1016/j.solmat.2005.05.011

DO - 10.1016/j.solmat.2005.05.011

M3 - Article

AN - SCOPUS:33344467793

SN - 0927-0248

VL - 90

SP - 916

EP - 922

JO - Solar Energy Materials and Solar Cells

JF - Solar Energy Materials and Solar Cells

IS - 7-8

ER -

Synthesis and photovoltaic properties of mono-substituted quaterthiophenes bearing strong electron-withdrawing group

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