Synthesis of unsymmetrical biaryls by electroreductive cobalt-catalyzed cross-coupling of aryl halides

Paulo Gomes; Hyacinthe Fillon; Corinne Gosmini; Eric Labbé; Jacques Périchon

doi:10.1016/S0040-4020(02)01030-X

Synthesis of unsymmetrical biaryls by electroreductive cobalt-catalyzed cross-coupling of aryl halides

Paulo Gomes
, Hyacinthe Fillon
, Corinne Gosmini
, Eric Labbé
, Jacques Périchon

Institut de Chimie et des Matériaux de Paris Est, CNRS UPEC/UMR 7182

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The consumable anode process allows the electrochemical cross-coupling reaction between various functionalized aromatic halides (iodides, bromides and chlorides) in the presence of cobalt halides as catalyst in a mixed solvent acetonitrile/pyridine (9:1). A great variety of unsymmetrical biaryls are obtained in moderate to excellent yields.

langue originale	Anglais
Pages (de - à)	8417-8424
Nombre de pages	8
journal	Tetrahedron
Volume	58
Numéro de publication	42
Les DOIs	https://doi.org/10.1016/S0040-4020(02)01030-X
état	Publié - 14 oct. 2002
Modification externe	Oui

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10.1016/S0040-4020(02)01030-X

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title = "Synthesis of unsymmetrical biaryls by electroreductive cobalt-catalyzed cross-coupling of aryl halides",

abstract = "The consumable anode process allows the electrochemical cross-coupling reaction between various functionalized aromatic halides (iodides, bromides and chlorides) in the presence of cobalt halides as catalyst in a mixed solvent acetonitrile/pyridine (9:1). A great variety of unsymmetrical biaryls are obtained in moderate to excellent yields.",

keywords = "Aryl halides, Biaryls, Cobalt, Electron-withdrawing group",

author = "Paulo Gomes and Hyacinthe Fillon and Corinne Gosmini and Eric Labb{\'e} and Jacques P{\'e}richon",

year = "2002",

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doi = "10.1016/S0040-4020(02)01030-X",

language = "English",

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pages = "8417--8424",

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T1 - Synthesis of unsymmetrical biaryls by electroreductive cobalt-catalyzed cross-coupling of aryl halides

AU - Gomes, Paulo

AU - Fillon, Hyacinthe

AU - Gosmini, Corinne

AU - Labbé, Eric

AU - Périchon, Jacques

PY - 2002/10/14

Y1 - 2002/10/14

N2 - The consumable anode process allows the electrochemical cross-coupling reaction between various functionalized aromatic halides (iodides, bromides and chlorides) in the presence of cobalt halides as catalyst in a mixed solvent acetonitrile/pyridine (9:1). A great variety of unsymmetrical biaryls are obtained in moderate to excellent yields.

AB - The consumable anode process allows the electrochemical cross-coupling reaction between various functionalized aromatic halides (iodides, bromides and chlorides) in the presence of cobalt halides as catalyst in a mixed solvent acetonitrile/pyridine (9:1). A great variety of unsymmetrical biaryls are obtained in moderate to excellent yields.

KW - Aryl halides

KW - Biaryls

KW - Cobalt

KW - Electron-withdrawing group

UR - https://www.scopus.com/pages/publications/0037078262

U2 - 10.1016/S0040-4020(02)01030-X

DO - 10.1016/S0040-4020(02)01030-X

M3 - Article

AN - SCOPUS:0037078262

SN - 0040-4020

VL - 58

SP - 8417

EP - 8424

JO - Tetrahedron

JF - Tetrahedron

IS - 42

ER -

Synthesis of unsymmetrical biaryls by electroreductive cobalt-catalyzed cross-coupling of aryl halides

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