The π-Distortive Propensities in Benzene and the Allyl Radical. A Reply to a Criticism

Philippe C. Hiberty; Gilles Ohanessian; Jean Michel Lefour; Sason S. Shaik

doi:10.1021/jo00370a035

The π-Distortive Propensities in Benzene and the Allyl Radical. A Reply to a Criticism

Philippe C. Hiberty
, Gilles Ohanessian
, Jean Michel Lefour
, Sason S. Shaik

CNRS
Ben Gurion University of the Negev

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The criticism in the preceding paper is answered. To prove instability of a structure toward a localizing distortion mode it is sufficient to identify one such distortion mode that lowers the energy of the delocalized structure. Aromaticity and π-distortive propensity in C₆H₆ are unrelated properties that coexist in harmony and must be explored by different means.

langue originale	Anglais
Pages (de - à)	3908-3909
Nombre de pages	2
journal	Journal of Organic Chemistry
Volume	51
Numéro de publication	20
Les DOIs	https://doi.org/10.1021/jo00370a035
état	Publié - 1 janv. 1986

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10.1021/jo00370a035

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title = "The π-Distortive Propensities in Benzene and the Allyl Radical. A Reply to a Criticism",

abstract = "The criticism in the preceding paper is answered. To prove instability of a structure toward a localizing distortion mode it is sufficient to identify one such distortion mode that lowers the energy of the delocalized structure. Aromaticity and π-distortive propensity in C6H6 are unrelated properties that coexist in harmony and must be explored by different means.",

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AU - Hiberty, Philippe C.

AU - Ohanessian, Gilles

AU - Lefour, Jean Michel

AU - Shaik, Sason S.

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Y1 - 1986/1/1

N2 - The criticism in the preceding paper is answered. To prove instability of a structure toward a localizing distortion mode it is sufficient to identify one such distortion mode that lowers the energy of the delocalized structure. Aromaticity and π-distortive propensity in C6H6 are unrelated properties that coexist in harmony and must be explored by different means.

AB - The criticism in the preceding paper is answered. To prove instability of a structure toward a localizing distortion mode it is sufficient to identify one such distortion mode that lowers the energy of the delocalized structure. Aromaticity and π-distortive propensity in C6H6 are unrelated properties that coexist in harmony and must be explored by different means.

U2 - 10.1021/jo00370a035

DO - 10.1021/jo00370a035

M3 - Article

AN - SCOPUS:0001733832

SN - 0022-3263

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 20

ER -

The π-Distortive Propensities in Benzene and the Allyl Radical. A Reply to a Criticism

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