The xanthate route to all-carbon quaternary centers

Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1007/s11426-019-9587-x

The xanthate route to all-carbon quaternary centers

Béatrice Quiclet-Sire
, Samir Z. Zard

Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article de révision › Revue par des pairs

15 Citations (Scopus)

Résumé

This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.

langue originale	Anglais
Pages (de - à)	1450-1462
Nombre de pages	13
journal	Science China Chemistry
Volume	62
Numéro de publication	11
Les DOIs	https://doi.org/10.1007/s11426-019-9587-x
état	Publié - 1 nov. 2019
Modification externe	Oui

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title = "The xanthate route to all-carbon quaternary centers",

abstract = "This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.",

keywords = "cyclization, quaternary centers, radical addition, tandem reactions, xanthates",

author = "B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

note = "Publisher Copyright: {\textcopyright} 2019, Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature.",

year = "2019",

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doi = "10.1007/s11426-019-9587-x",

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AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

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N2 - This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.

AB - This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.

KW - cyclization

KW - quaternary centers

KW - radical addition

KW - tandem reactions

KW - xanthates

U2 - 10.1007/s11426-019-9587-x

DO - 10.1007/s11426-019-9587-x

M3 - Review article

AN - SCOPUS:85074088768

SN - 1674-7291

VL - 62

SP - 1450

EP - 1462

JO - Science China Chemistry

JF - Science China Chemistry

IS - 11

ER -

The xanthate route to all-carbon quaternary centers

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