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Thermal and mechanical properties of epoxy/polyurethane blend system initiated by cationic latent thermal catalyst

  • Inha University
  • Center for Convergent Research of Emerging Virus Infection
  • Korea National University of Transportation

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Résumé

In this work, the blend of diglycidylether of bisphenol A (DGEBA) and modified Polyurethane (PU) was prepared and characterized the cure behavior and mechanical interfacial properties. The N-benzylpyrazinium hexafiuoroantimonate was used as a cationic initiator for cure, and the content of PU was varied within 0-20 phr. The cure behavior and mechanical interfacial properties were studied by DSC and the critical stress intensity actor (KIC) measurements. Also thermal stabilities were carried out by TMA and TGA analyses. It is found that the cure activation energy (Ea) was slightly increased on increasing the PU content, and a maximum value was noted at 10 phr PU. The mechanical interfacial properties measured from KIC showed a similar behavior with the results of conversion. These results were probably due to the increase of the hydrogen bonding between the hydroxyl groups of DGEBA and isocyanate groups in PU.

langue originaleAnglais
titreNanocomposites and Nanoporous Materials - ISNAM7 - Proceedings of the 7th International Symposium on Nanocomposites and Nanoporous Materials (ISNAM7)
EditeurTrans Tech Publications Ltd
Pages215-218
Nombre de pages4
ISBN (imprimé)3908451272, 9783908451273
Les DOIs
étatPublié - 1 janv. 2007
Modification externeOui
Evénement7th International Symposium on Nanocomposites and Nanoporous Materials 2006, ISNAM7 - Gyeongju, Corée du Sud
Durée: 15 févr. 200617 févr. 2006

Série de publications

NomSolid State Phenomena
Volume119
ISSN (imprimé)1012-0394

Une conférence

Une conférence7th International Symposium on Nanocomposites and Nanoporous Materials 2006, ISNAM7
Pays/TerritoireCorée du Sud
La villeGyeongju
période15/02/0617/02/06

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