Three-component metal-free arylation of isocyanides

Unnamatla M.V. Basavanag; Aurélie Dos Santos; Laurent El Kaim; Rocio Gámez-Montaño; Laurence Grimaud

doi:10.1002/anie.201302659

Three-component metal-free arylation of isocyanides

Unnamatla M.V. Basavanag
, Aurélie Dos Santos
, Laurent El Kaim
, Rocio Gámez-Montaño
, Laurence Grimaud

Universidad de Guanajuato
Laboratoire de Synthèse Organique
CNRS

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

Mumm's the word: The title reaction can be performed by the addition of isocyanides to benzenediazonium salts in the presence of sodium or potassium carboxylates. The reaction involves nitrilium intermediates which may be trapped by water or carboxylic acids to form amides and imides, respectively, after Mumm rearrangement.

langue originale	Anglais
Pages (de - à)	7194-7197
Nombre de pages	4
journal	Angewandte Chemie - International Edition
Volume	52
Numéro de publication	28
Les DOIs	https://doi.org/10.1002/anie.201302659
état	Publié - 8 juil. 2013
Modification externe	Oui

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10.1002/anie.201302659

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title = "Three-component metal-free arylation of isocyanides",

abstract = "Mumm's the word: The title reaction can be performed by the addition of isocyanides to benzenediazonium salts in the presence of sodium or potassium carboxylates. The reaction involves nitrilium intermediates which may be trapped by water or carboxylic acids to form amides and imides, respectively, after Mumm rearrangement.",

keywords = "arylation, isocyanides, reaction mechanisms, rearrangement, synthetic methods",

author = "Basavanag, \{Unnamatla M.V.\} and \{Dos Santos\}, Aur{\'e}lie and \{El Kaim\}, Laurent and Rocio G{\'a}mez-Monta{\~n}o and Laurence Grimaud",

year = "2013",

month = jul,

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doi = "10.1002/anie.201302659",

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journal = "Angewandte Chemie - International Edition",

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T1 - Three-component metal-free arylation of isocyanides

AU - Basavanag, Unnamatla M.V.

AU - Dos Santos, Aurélie

AU - El Kaim, Laurent

AU - Gámez-Montaño, Rocio

AU - Grimaud, Laurence

PY - 2013/7/8

Y1 - 2013/7/8

N2 - Mumm's the word: The title reaction can be performed by the addition of isocyanides to benzenediazonium salts in the presence of sodium or potassium carboxylates. The reaction involves nitrilium intermediates which may be trapped by water or carboxylic acids to form amides and imides, respectively, after Mumm rearrangement.

AB - Mumm's the word: The title reaction can be performed by the addition of isocyanides to benzenediazonium salts in the presence of sodium or potassium carboxylates. The reaction involves nitrilium intermediates which may be trapped by water or carboxylic acids to form amides and imides, respectively, after Mumm rearrangement.

KW - arylation

KW - isocyanides

KW - reaction mechanisms

KW - rearrangement

KW - synthetic methods

UR - https://www.scopus.com/pages/publications/84880141994

U2 - 10.1002/anie.201302659

DO - 10.1002/anie.201302659

M3 - Article

AN - SCOPUS:84880141994

SN - 1433-7851

VL - 52

SP - 7194

EP - 7197

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 28

ER -

Three-component metal-free arylation of isocyanides

Résumé

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