Trifluoroacetonyl radicals: A versatile approach to trifluoromethyl ketones

Marie Pierre Denieul; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1039/cc9960002511

Trifluoroacetonyl radicals: A versatile approach to trifluoromethyl ketones

Marie Pierre Denieul
, Béatrice Quiclet-Sire
, Samir Z. Zard

CNRS
Laboratoire de Synthèse Organique

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

38 Citations (Scopus)

Résumé

Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trifluoromethyl ketones in good yields.

langue originale	Anglais
Pages (de - à)	2511-2512
Nombre de pages	2
journal	Chemical Communications
Numéro de publication	22
Les DOIs	https://doi.org/10.1039/cc9960002511
état	Publié - 1 janv. 1996

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10.1039/cc9960002511

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title = "Trifluoroacetonyl radicals: A versatile approach to trifluoromethyl ketones",

abstract = "Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trifluoromethyl ketones in good yields.",

author = "Denieul, \{Marie Pierre\} and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "1996",

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doi = "10.1039/cc9960002511",

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journal = "Chemical Communications",

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T1 - Trifluoroacetonyl radicals

T2 - A versatile approach to trifluoromethyl ketones

AU - Denieul, Marie Pierre

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trifluoromethyl ketones in good yields.

AB - Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trifluoromethyl ketones in good yields.

U2 - 10.1039/cc9960002511

DO - 10.1039/cc9960002511

M3 - Article

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SN - 1359-7345

SP - 2511

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JO - Chemical Communications

JF - Chemical Communications

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Trifluoroacetonyl radicals: A versatile approach to trifluoromethyl ketones

Résumé

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