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Ultrafast changes in the far-infrared conductivity of carbon nanotubes

  • C. Frischkorn
  • , T. Kampfrath
  • , K. Von Volkmann
  • , L. Perfetti
  • , M. Wolf
  • Free University of Berlin

Résultats de recherche: Le chapitre dans un livre, un rapport, une anthologie ou une collectionContribution à une conférenceRevue par des pairs

Résumé

The ultrafast charge-carrier dynamics in single-wall carbon nanotubes (NTs) have been investigated by time-resolved THz spectroscopy. Both the equilibrium and non-equilibrium conductivity data of the NTs in the far-infrared (FIR) spectral range from 1 to 40 THz are dominated by optical transitions across the band gap of tubes with gap energies of ∼ 10 meV. A simple model based on an ensemble of two-level systems excellently explains all experimental findings. In particular, the surprisingly weak temperature dependence of the FIR conductivity has been shown to arise from tube-to-tube variation of the chemical potential which is ∼ 100 meV in our sample. The results strongly suggest to use the temperature dependence of the FIR conductivity as a very sensitive and contact-free probe of the NT sample purity. Finally, the relaxation of the photo-excited NT sheet on a picosecond time scale mainly reflects the cooling of hot phonons which is about five times faster than in graphite. This points to much stronger lattice anharmonicities in NTs.

langue originaleAnglais
titre33rd International Conference on Infrared and Millimeter Waves and the 16th International Conference on Terahertz Electronics, 2008, IRMMW-THz 2008
Les DOIs
étatPublié - 31 déc. 2008
Modification externeOui
Evénement33rd International Conference on Infrared and Millimeter Waves and the 16th International Conference on Terahertz Electronics, 2008, IRMMW-THz 2008 - Pasadena, CA, États-Unis
Durée: 15 sept. 200819 sept. 2008

Série de publications

Nom33rd International Conference on Infrared and Millimeter Waves and the 16th International Conference on Terahertz Electronics, 2008, IRMMW-THz 2008

Une conférence

Une conférence33rd International Conference on Infrared and Millimeter Waves and the 16th International Conference on Terahertz Electronics, 2008, IRMMW-THz 2008
Pays/TerritoireÉtats-Unis
La villePasadena, CA
période15/09/0819/09/08

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