Unconventional oxazole formation from isocyanides

Aurélie Dos Santos; Laurent El Kaïm; Laurence Grimaud; Caroline Ronsseray

doi:10.1039/b904699b

Unconventional oxazole formation from isocyanides

Aurélie Dos Santos
, Laurent El Kaïm
, Laurence Grimaud
, Caroline Ronsseray

Unité Chimie et Procédés

Résultats de recherche: Contribution à un journal › Article › Revue par des pairs

Résumé

The coupling of an acyl chloride with an isocyanide affords 2,5-disubstituted oxazoles under mild basic conditions instead of 4,5-disubstituted derivatives when using Schöllkopf conditions (butyllithium); this reaction constitutes a remarkable example of a base-induced chemoselective process in isocyanide chemistry.

langue originale	Anglais
Pages (de - à)	3907-3909
Nombre de pages	3
journal	Chemical Communications
Numéro de publication	26
Les DOIs	https://doi.org/10.1039/b904699b
état	Publié - 1 janv. 2009
Modification externe	Oui

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10.1039/b904699b

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title = "Unconventional oxazole formation from isocyanides",

abstract = "The coupling of an acyl chloride with an isocyanide affords 2,5-disubstituted oxazoles under mild basic conditions instead of 4,5-disubstituted derivatives when using Sch{\"o}llkopf conditions (butyllithium); this reaction constitutes a remarkable example of a base-induced chemoselective process in isocyanide chemistry.",

author = "\{Dos Santos\}, Aur{\'e}lie and \{El Ka{\"i}m\}, Laurent and Laurence Grimaud and Caroline Ronsseray",

year = "2009",

month = jan,

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doi = "10.1039/b904699b",

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T1 - Unconventional oxazole formation from isocyanides

AU - Dos Santos, Aurélie

AU - El Kaïm, Laurent

AU - Grimaud, Laurence

AU - Ronsseray, Caroline

PY - 2009/1/1

Y1 - 2009/1/1

N2 - The coupling of an acyl chloride with an isocyanide affords 2,5-disubstituted oxazoles under mild basic conditions instead of 4,5-disubstituted derivatives when using Schöllkopf conditions (butyllithium); this reaction constitutes a remarkable example of a base-induced chemoselective process in isocyanide chemistry.

AB - The coupling of an acyl chloride with an isocyanide affords 2,5-disubstituted oxazoles under mild basic conditions instead of 4,5-disubstituted derivatives when using Schöllkopf conditions (butyllithium); this reaction constitutes a remarkable example of a base-induced chemoselective process in isocyanide chemistry.

UR - https://www.scopus.com/pages/publications/67650616209

U2 - 10.1039/b904699b

DO - 10.1039/b904699b

M3 - Article

C2 - 19662248

AN - SCOPUS:67650616209

SN - 1359-7345

SP - 3907

EP - 3909

JO - Chemical Communications

JF - Chemical Communications

IS - 26

ER -

Unconventional oxazole formation from isocyanides

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